Site-selective luminescence spectroscopy of bound excitons and local band structure of chlorine intercalated 2H-and 3R-MoS2 polytypes
| Autor: | K. Sushkevich, Elena Mishina, Yu. Chumakov, Paulina Plochocka, S. Anghel, Anatolie A. Mitioglu, Leonid Kulyuk, G. Volodina, Victor Ch. Kravtsov |
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| Rok vydání: | 2016 |
| Předmět: |
Photoluminescence
Chemistry Exciton Intercalation (chemistry) Inorganic chemistry Biophysics 02 engineering and technology General Chemistry Correlated Electron Systems / High Field Magnet Laboratory (HFML) 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Biochemistry Atomic and Molecular Physics and Optics 0104 chemical sciences Crystallography chemistry.chemical_compound Molecule 0210 nano-technology Electronic band structure Spectroscopy Luminescence Molybdenum disulfide |
| Zdroj: | Journal of Luminescence, 177, pp. 331-336 Journal of Luminescence, 177, 331-336 |
| ISSN: | 0022-2313 |
| Popis: | Photoluminescence and X-ray diffraction are used to investigate 2H and 3R polytypes of MoS2 layered crystals intercalated with Cl2 molecules. The spectral structure of the observed bound excitons emission is individual for each polytype, which can be used for unambiguous identification of the 2H and 3R polytypes. The DFT band structure calculations have been done for three molecular layers of 2H-MoS2 and 3R-MoS2 polytypes with and without intercalation of Cl2 molecules. The spectroscopic experimental results confirmed theoretical calculations performed for both cases and it has been demonstrated that halogen intercalation completely changes the local band structure of both 2H- and 3R-MoS2 polytypes. |
| Databáze: | OpenAIRE |
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