X-ray Absorption Fine Structure Evidence for Amorphous Zinc Sulfide as a Major Zinc Species in Suspended Matter from the Seine River Downstream of Paris, Ile-de-France, France
| Autor: | Guillaume Morin, Fabien Maillot, Olivier Proux, Cindy Rianti Priadi, Farid Juillot, Sophie Ayrault, Isabelle Llorens, Denis Testemale, Rebecca Hochreutener, Pierre Le Pape, Gordon E. Brown |
|---|---|
| Rok vydání: | 2012 |
| Předmět: |
Geologic Sediments
Paris 010504 meteorology & atmospheric sciences chemistry.chemical_element Electrons Zinc Sulfides 010501 environmental sciences 01 natural sciences chemistry.chemical_compound Water column Rivers Suspensions Environmental Chemistry 0105 earth and related environmental sciences Fourier Analysis Extended X-ray absorption fine structure Chemistry Water General Chemistry Particulates Nitrogen Zinc sulfide Sulfur 6. Clean water X-ray absorption fine structure Oxygen X-Ray Absorption Spectroscopy Zinc Compounds Environmental chemistry Linear Models Microscopy Electron Scanning Particulate Matter Water Pollutants Chemical |
| Zdroj: | Environmental Science & Technology. 46:3712-3720 |
| ISSN: | 1520-5851 0013-936X |
| Popis: | Zinc is one of the most widespread trace metals (TMs) in Earth surface environments and is the most concentrated TM in the downstream section of the Seine River (France) due to significant anthropogenic input from the Paris conurbation. In order to better identify the sources and cycling processes of Zn in this River basin, we investigated seasonal and spatial variations of Zn speciation in suspended particulate matter (SPM) in the oxic water column of the Seine River from upstream to downstream of Paris using synchrotron-based extend X-ray absorption fine structure (EXAFS) spectroscopy at the Zn K-edge. First-neighbor contributions to the EXAFS were analyzed in SPM samples, dried and stored under a dry nitrogen atmosphere or under an ambient oxygenated atmosphere. We found a sulfur first coordination environment around Zn (in the form of amorphous zinc sulfide) in the raw SPM samples stored under dry nitrogen vs an oxygen first coordination environment around Zn in the samples stored in an oxygenated atmosphere. These findings are supported by scanning electron microscopy and energy dispersive X-ray spectrometry observations. Linear combination fitting of the EXAFS data for SPM samples, using a large set of EXAFS spectra of Zn model compounds, indicates dramatic changes in the Zn speciation from upstream to downstream of Paris, with amorphous ZnS particles becoming dominant dowstream. In contrast, Zn species associated with calcite (either adsorbed or incorporated in the structure) are dominant upstream. Other Zn species representing about half of the Zn pool in the SPM consist of Zn-sorbed on iron oxyhydroxides (ferrihydrite and goethite) and, to a lesser extent, Zn-Al layered double hydroxides, Zn incorporated in dioctahedral layers of clay minerals and Zn sorbed to amorphous silica. Our results highlight the importance of preserving the oxidation state in TM speciation studies when sampling suspended matter, even in an oxic water column. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|