Distance-Independent DNA Charge Transport across an Adenine Tract

Autor:	Jacqueline K. Barton, Katherine E. Augustyn, Joseph C. Genereux
Rok vydání:	2007
Předmět:	Molecular Structure Adenine Attenuation Static Electricity chemistry.chemical_element Charge (physics) DNA General Chemistry Molecular physics Catalysis Rhodium chemistry.chemical_compound Delocalized electron Biochemistry chemistry Yield (chemistry) Chromatography High Pressure Liquid
Zdroj:	Angewandte Chemie International Edition. 46:5731-5733
ISSN:	1521-3773 1433-7851
Popis:	Charging along: DNA-mediated charge transport across adenine tracts is monitored by using a probe interior to the bridge (N^6-cyclopropyladenine (^(CP)A), shown in red). This trap was incorporated serially across the bridge and could be oxidized by a distal rhodium photooxidant without significant attenuation in yield over a distance of 5 nm. These results are consistent with complete delocalization of charge across the DNA bridge.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e9fbf1f9864634f1b1ebc3296bb0de49 https://doi.org/10.1002/anie.200701522 Zobrazit plný text záznamu Plný text