Electrochemical deposition and characterization of Zn-Fe alloys
Autor: | B Jelena Bajat, M Dragutin Drazic, B Vesna Miskovic-Stankovic, P Slavica Zec, D Miodrag Maksimovic |
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Rok vydání: | 2004 |
Předmět: |
Materials science
Zn-Fe alloy Alloy Analytical chemistry zn–fe alloy 02 engineering and technology engineering.material Zn–Fe alloy 010402 general chemistry Electrochemistry 01 natural sciences Corrosion lcsh:Chemistry Polarization (electrochemistry) Chemical composition corrosion General Chemistry 021001 nanoscience & nanotechnology 0104 chemical sciences lcsh:QD1-999 Linear sweep voltammetry engineering electrodeposition Surface modification 0210 nano-technology Current density surface modification |
Zdroj: | Journal of the Serbian Chemical Society Journal of the Serbian Chemical Society, Vol 69, Iss 10, Pp 807-815 (2004) |
Popis: | Zn–Fe alloy electrochemically deposited on steel under various deposition conditions were investigated using anodic linear sweep voltammetry (ALSV) and X-ray diffraction (XRD) analysis for phase structure determination, energy dispersive X-ray (EDX) analysis for determination of chemical composition and polarization measurements and open circuit potential measurements for determination of corrosion properties. The influence of deposition current density on the chemical composition, phase structure and corrosion stability of Zn–Fe alloys was studied. It was shown that deposition current density strongly affects the corrosion stability of Zn–Fe alloys, while Zn–Fe alloy electrodeposited at 4Adm-2 exhibited the lowest corrosion rate. Legure Zn–Fe elektrohemijski taložene na čeliku pod različitim uslovima ispitivane su primenom anodne linearne promene potencijala i difrakcije X-zraka, za određivanje fazne strukture, spektroskopije energetski dispergovanih X-zraka, za određivanje hemijskog sastava i polarizacionih merenja kao i merenja potencijala otvorenog kola, za određivanje korozione stabilnosti. Proučavan je uticaj gustine struje taloženja na hemijski sastav fazne strukture i korozionu stabilnost Zn–Fe legura. Pokazano je da gustina struje taloženja veoma utiče na korozionu stabilnost Zn–Fe legura, i da legura taložena gustinom struje od 4 Adm-2 ima najmanju brzinu korozije. |
Databáze: | OpenAIRE |
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