Heterogenisation of polyoxometalates and other metal-based complexes in metal–organic frameworks: from synthesis to characterisation and applications in catalysis
| Autor: | Olivier Oms, Caroline Mellot-Draznieks, Y. Benseghir, M. Duguet, Anne Dolbecq, Pierre Mialane, P. Gairola |
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| Přispěvatelé: | Institut Lavoisier de Versailles (ILV), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Chimie des Processus Biologiques (LCPB), Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), ANR-11-LABX-0039,CHARMMMAT,CHimie des ARchitectures MoléculairesMultifonctionnelles et des MATériaux(2011) |
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
Materials science
Nanotechnology 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Electrocatalyst 01 natural sciences Redox 0104 chemical sciences Catalysis Metal Homogeneous visual_art visual_art.visual_art_medium [CHIM]Chemical Sciences Metal-organic framework 0210 nano-technology Selectivity |
| Zdroj: | Chemical Society Reviews Chemical Society Reviews, Royal Society of Chemistry, 2021, ⟨10.1039/d0cs00323a⟩ |
| ISSN: | 0306-0012 1460-4744 |
| DOI: | 10.1039/d0cs00323a⟩ |
| Popis: | International audience; These last years have seen a huge growing interest in the heterogenisation of molecular catalysts since it allows combining the advantages of homogeneous and heterogeneous catalysis. Besides bringing recyclability, the immobilisation of the catalyst may increase its stability while allowing tuning its selectivity. In this respect, Metal-Organic Frameworks (MOFs) attract an evergrowing interest as a platform for their confinement within their pores or channels. In this review, Cat@MOF composites whereby molecular catalysts (Cats) are immobilised in MOFs through non-covalent interactions with their host, are reviewed thoroughly. Polyoxometalates (POMs) and other metal-based complexes as immobilised molecular species are covered. In the first part, the different synthetic methods and analytical tools are described. A critical analysis of the various physico-chemical methods available to characterise the Cat@MOF composites is provided-a particular attention being paid toward their pertinence for the investigation of the content, the position and the stability of the catalyst within the MOF. Besides, focus is made on non-conventional techniques such as Pair Distribution Function (PDF) and a section is dedicated to the contribution of DFT calculations. In the second part, the applications of these materials in the fields of catalysis, including oxidation and reduction reactions, acid-base catalysis, photo-and electrocatalysis are detailed. |
| Databáze: | OpenAIRE |
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