Crystal structure of 2-azaniumyl-3-bromo-6-oxo-5,6-dihydropyrido[1,2-a]quinoxalin-11-ium dibromide
| Autor: | Turganbay S. Iskenderov, Natalia O. Sharkina, Md. Serajul Haque Faizi |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: |
chemistry.chemical_classification
crystal structure Bromine Chemistry Hydrogen bond Maximum deviation Salt (chemistry) chemistry.chemical_element C—H⋯Br interactions General Chemistry Crystal structure Condensed Matter Physics Medicinal chemistry Data Reports Crystal C—H...Br interactions lcsh:Chemistry chemistry.chemical_compound lcsh:QD1-999 Bromide Organic chemistry General Materials Science pyrido[1 2-a]quinoxalin-11-ium Methanol bromide |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 1, Pp o17-o18 (2015) Acta Crystallographica Section E: Crystallographic Communications |
| ISSN: | 2056-9890 |
| Popis: | The title salt, C12H10BrN3O2+·2Br−, was synthesized from the reaction ofN1,N4-bis(pyridin-2-ylmethylidene)benzene-1,4-diamine and bromine in a methanol solution. All non-H atoms of the 2-azaniumyl-3-bromo-6-oxo-5,6-dihydropyrido[1,2-a]quinoxalin-11-ium cation are nearly coplanar, the maximum deviation being 0.114 (4) Å. In the crystal, the cations and anions are linked through N—H...Br hydrogen bonds and weak C—H...Br interactions, forming a three-dimensional supramolecular architecture. A short Br...Br contact [3.3088 (9) Å] is observed in the crystal. |
| Databáze: | OpenAIRE |
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