The continuous synthesis and application of graphene supported palladium nanoparticles: a highly effective catalyst for Suzuki-Miyaura cross-coupling reactions
| Autor: | Michael Burkholder, Ali R. Siamaki, Kendra W. Brinkley, Katherine Belecki, B. Frank Gupton |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: |
Materials science
Renewable Energy Sustainability and the Environment Graphene flow chemistry Health Toxicology and Mutagenesis General Chemical Engineering graphene Palladium nanoparticles chemistry.chemical_element Flow chemistry Photochemistry palladium Industrial and Manufacturing Engineering Coupling reaction law.invention Catalysis Chemistry Fuel Technology solid supported catalysis suzuki-miyaura cross-coupling chemistry law Environmental Chemistry QD1-999 Palladium |
| Zdroj: | Green Processing and Synthesis, Vol 4, Iss 3, Pp 241-246 (2015) |
| ISSN: | 2191-9550 2191-9542 |
| Popis: | An efficient, sustainable, and continuous method for the preparation of graphene supported palladium nanoparticles (Pd/G) has been developed using microwave irradiation as a heating source for the metal deposition process. The Pd/G produced from this method was effective in Suzuki-Miyaura cross-coupling reactions with a broad range of substrates. When incorporated into a packed bed flow reactor, this ligand free catalyst system continued to demonstrate high reaction conversions with limited catalyst leaching in the reaction mixture (347 ppb palladium). |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|