Synthesis of Trifluoromethanesulfinamidines and -sulfanylamides

Autor:	Bernard R. Langlois, Thierry Billard, Eric Bacque, Aurelien Ferry
Rok vydání:	2008
Předmět:	Magnetic Resonance Spectroscopy Primary (chemistry) Molecular Structure Nitrogen Organic Chemistry Chemistry Organic Fluorine Amides Combinatorial chemistry Chemical synthesis Fluorides chemistry.chemical_compound Models Chemical Sulfinamide chemistry Reagent Molecule Sulfur
Zdroj:	The Journal of Organic Chemistry. 73:9362-9365
ISSN:	1520-6904 0022-3263
DOI:	10.1021/jo8018544
Popis:	Fluorinated moieties constitute important substituents used in many applications to modify the properties of molecules. The action of DAST onto Ruppert's reagent yields to a not isolable intermediate that can then react with various primary amines to give trifluoromethanesulfinamidines and trifluoromethanesulfanylamides. Such compounds were unknown until now and constitute interesting new families of fluorinated molecules.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e980e2c2cc6d2b281af225df6cd922fe https://doi.org/10.1021/jo8018544 Zobrazit plný text záznamu