Do 2-coordinate iodine(i) and silver(i) complexes form nucleophilic iodonium interactions (NIIs) in solution?

Autor:	Scott Wilcox, Daniel Sethio, Jas S. Ward, Antonio Frontera, Roland Lindh, Kari Rissanen, Máté Erdélyi
Rok vydání:	2022
Předmět:	Magnetic Resonance Spectroscopy Silver Cations Materials Chemistry Metals and Alloys Ceramics and Composites General Chemistry Iodides Catalysis Iodine Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical Communications. 58:4977-4980
ISSN:	1364-548X 1359-7345
DOI:	10.1039/d2cc00994c
Popis:	The interaction of a [bis(pyridine)iodine(i)]+ cation with a [bis(pyridine)silver(i)]+ cation, in which an iodonium ion acts as a nucleophile by transferring electron density to the silver(i) cation, is reinvestigated herein.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e9528e20ba91ea004a438d240b6e6c83 https://doi.org/10.1039/d2cc00994c Zobrazit plný text záznamu