Copper and Nickel Nanoparticles Prepared by Thermal Treatment of Their Respective Cations Confined in Nanopores through High-Pressure Synthesis
| Autor: | Nicolas Pasternak, Marianne Bombled, Nancy Brodie-Linder, Patricia Beaunier, Johnny Deschamps, Christiane Alba-Simionesco, Fabrice Audonnet |
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| Přispěvatelé: | Laboratoire Léon Brillouin (LLB - UMR 12), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Biomolécules : Conception, Isolement, Synthèse (BioCIS), Institut de Chimie du CNRS (INC)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-CY Cergy Paris Université (CY), Unité de Chimie et Procédés (UCP), École Nationale Supérieure de Techniques Avancées (ENSTA Paris), Institut Pascal (IP), Centre National de la Recherche Scientifique (CNRS)-Université Clermont Auvergne (UCA)-Institut national polytechnique Clermont Auvergne (INP Clermont Auvergne), Université Clermont Auvergne (UCA)-Université Clermont Auvergne (UCA), Laboratoire de Réactivité de Surface (LRS), Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS)-Université Paris-Saclay |
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
Thermogravimetric analysis
Technology Materials science Geography Planning and Development chemistry.chemical_element 02 engineering and technology Thermal treatment MCM–41 mesoporous materials 010402 general chemistry 01 natural sciences Metal Adsorption hydrophobic Fourier transform infrared spectroscopy nickel II [CHIM.MATE]Chemical Sciences/Material chemistry 021001 nanoscience & nanotechnology Copper 0104 chemical sciences Nickel high pressure chemistry Chemical engineering visual_art visual_art.visual_art_medium copper II Selected area diffraction 0210 nano-technology thermal treatment surface modification |
| Zdroj: | Applied Nano, Vol 2, Iss 20, Pp 278-288 (2021) Applied Nano Volume 2 Issue 3 Pages 20-288 Applied Nano, 2021, 2 (3), pp.278-288. ⟨10.3390/applnano2030020⟩ Applied Nano, MDPI, 2021, 2 (3), pp.278-288. ⟨10.3390/applnano2030020⟩ |
| ISSN: | 2673-3501 |
| Popis: | International audience; A new and simple method for preparing confined copper and nickel nanoparticles by thermal treatment of their respective cations inside Mobil Composition of Matter 41 (MCM–41) hydrophobic nanopores is presented here. Surface modified MCM–41 hydrophobic materials were impregnated by using high-pressure treatment with copper II (Cu II) or nickel II (Ni II) aqueous solutions. After pressure release and washing, the remaining metal cations, confined exclusively within the nanopores, were heated, forming metallic nanoparticles. Reduction of the cations by a redox reaction between the hydrophobic organic surface and the confined metal cations is proposed. Transmission electronic microscopy (TEM), selected area electron diffraction (SAED), nitrogen (N2) adsorption at −196 °C (77 K), Fourier transform infrared (FTIR) and thermogravimetric (TGA) analyses evidenced the identification of copper and nickel nanoparticles (NPs). |
| Databáze: | OpenAIRE |
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