Multiple polymerization – formation of hybrid materials consisting of two or more polymers from one monomer
| Autor: | Rico John, Thomas Ebert, Stefan Spange, A. Seifert, A. Wollbrink |
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| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: |
Materials science
Polymers and Plastics Bulk polymerization Organic Chemistry Bioengineering Solution polymerization Chain transfer 02 engineering and technology Polymerisation Nanostruktur Sol-Gel-Verfahren Organisch-anorganischer Hybridwerkstoff Physisorption Kohlenstoff Phenoplast 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Biochemistry 0104 chemical sciences Zwillingspolymerisation Mehrlingspolymeriation Nanostrukturen Hybridmaterialien Kompositmaterialien poröse Materialien Stickstoffsorption Chain-growth polymerization Polymerization twin polymerization multiple polymerization nanostructure hybrid materials composite materials porous materials nitrogen sorption Polymer chemistry ddc:540 Precipitation polymerization Reversible addition−fragmentation chain-transfer polymerization 0210 nano-technology Ionic polymerization |
| Zdroj: | Polym. Chem., 2016,7, 6826-6833 |
| Popis: | Hybrid materials consisting of three different components were synthesized by the polymerization of one heterotrifunctional monomer in just one reaction step using, at the most, one catalyst. The polymerization of 2-furfuyloxy-2-methyl-4H-1,3,2-benzodioxasiline leading to a hybrid material consisting of phenolic resin, poly(furfuryl alcohol), and polymethylsilsesquioxane is, to the best of our knowledge, the first polymerization of this kind. The influence of different catalysts on the polymerization behavior and thus on the structure of the hybrid material was investigated. In accordance with the term “twin polymerization”, which is used for the polymerization of one monomer yielding two separate polymers, this type of polymerization could be called “triple polymerization”. The term “multiple polymerization” is introduced as a general term for the underlying concept of the synthesis of multiple polymers starting from one monomer in one process step. Dieser Beitrag ist aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich. |
| Databáze: | OpenAIRE |
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