Detachment dynamics of colloidal spheres with adhesive interactions
Autor: | Johan Bergenholtz |
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Rok vydání: | 2018 |
Předmět: |
Materials science
02 engineering and technology Mechanics 021001 nanoscience & nanotechnology 01 natural sciences Exponential function Colloid Exact solutions in general relativity Virial coefficient 0103 physical sciences Bound state SPHERES Adhesive Diffusion (business) 010306 general physics 0210 nano-technology |
Zdroj: | Physical Review E. 97 |
ISSN: | 2470-0053 2470-0045 |
DOI: | 10.1103/physreve.97.042610 |
Popis: | Escape of colloidal-size particles from various kinds of solids, such as aggregates and surfaces, occurs in a wide variety of settings of both fundamental and applied scientific interest. In this paper an exact solution for the detachment of adhesive spheres from each other by means of diffusion is presented. The solution takes into account repeated detachment and reattachment events in the course of time on the way toward the permanently separated state. For strongly adhesive spheres this state is approached in an exponential manner essentially regardless of how the bound state is specified. The analytical solution is shown to capture semiquantitatively the escape from more realistic potential wells using a mapping procedure whereby equality of second virial coefficients is imposed. |
Databáze: | OpenAIRE |
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