Crystal structure of 9-(dibromomethyl)-1,1-difluoro-3,7-dimethyl-1H-[1,3,5,2]oxadiazaborinino[3,4-a][1,8]naphthyridin-11-ium-1-uide
| Autor: | Yong Zhou, Shao Ming Chi, Jun Ping Zhou, Jian Song Luo, Bang Zhong Wang |
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| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
crystal structure
Crystallography 010405 organic chemistry Stereochemistry Hydrogen bond General Chemistry Crystal structure Meth 010402 general chemistry Condensed Matter Physics Ring (chemistry) hydrogen bonding 01 natural sciences Medicinal chemistry 0104 chemical sciences chemistry.chemical_compound chemistry QD901-999 1 8-naphthyridine BF2 complex General Materials Science Derivative (chemistry) Mirror plane |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 11, Pp 1642-1644 (2016) |
| ISSN: | 2056-9890 |
| Popis: | The molecule of the title 1,8-naphthyridine-BF2derivative, C12H10BBr2F2N3O, is located on a mirror plane running parallel to the entire ring system and the attached methyl C atoms. Individual molecules are stacked along theb-axis direction. The cohesion in the crystal structure is accomplished by C—H...F hydrogen bonds and additional off-set π–π interactions [centroid-to-centroid distance = 3.6392 (9) Å, slippage 0.472 Å], leading to the formation of a three-dimensional supramolecular network. |
| Databáze: | OpenAIRE |
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