Pentacarbonyl-2κ5 C-chlorido-1κCl-bis[1(η5)-cyclopentadienyl][μ-oxido(phenyl)methylene-1:2κ2 O:C]hafnium(IV)tungsten(0)
| Autor: | Catharine Esterhuysen, Stephanie Cronje, I.B.J. Nel |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: |
Metal-Organic Papers
chemistry.chemical_element General Chemistry Tungsten Condensed Matter Physics Ring (chemistry) Bioinformatics Medicinal chemistry Chloride Hafnium Metal chemistry.chemical_compound chemistry visual_art medicine visual_art.visual_art_medium General Materials Science Methylene medicine.drug |
| Zdroj: | Acta Crystallographica Section E: Structure Reports |
| ISSN: | 1600-5368 |
| Popis: | The title compound, [HfW(C5H5)2(C7H5O)Cl(CO)5] or [W(CO)5(C7H5O){Hf(C5H5)2Cl}], contains two metal centres, with a (tungstenpentacarbonyl)oxyphenylcarbene unit coordinated to a hafnocene chloride. The Hf—O—C angle is nearly linear, and the C=O distance is slightly shorter than for equivalent alkoxycarbenes. One of the cyclopentadienyl (Cp) rings undergoes an offset face-to-face π–π interaction [3.495 (7) Å] with the symmetry-related Cp ring of a neighbouring molecule. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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