Synthesis of diaryl ether components of ellagitannins using ortho-quinone with consonant mesomeric effects
| Autor: | Shintaro Matsumoto, Shinnosuke Wakamori, Tsukasa Hirokane, Hajime Hashimoto, Kazutada Ikeuchi, Hidetoshi Yamada, Hayato Konishi |
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| Rok vydání: | 2020 |
| Předmět: |
Diaryl ether
010405 organic chemistry Chemistry Metals and Alloys General Chemistry 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Quinone chemistry.chemical_compound Electrophile Materials Chemistry Ceramics and Composites Organic chemistry Reactivity (chemistry) Gallic acid |
| Zdroj: | Chemical Communications. 56:3991-3994 |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | Methods for synthesizing C-O digallate structures, the basic unit of diaryl ether components of natural ellagitannins, are described. In the designed building block derived from gallic acid, consonantly overlapped mesomeric effects enhanced its electrophilicity. This building block demonstrated substantial reactivity to improve the synthesis of dehydrodigalloyl, tergalloyl, and valoneoyl groups. |
| Databáze: | OpenAIRE |
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