Promoting water dissociation performance by borinic acid for the strong-acid/base-free hydrogen evolution reaction
| Autor: | Hai Xu, Xue-Yuan Wang, Xin-Hu Lv, Wen-Ming Wan, Yan Zhou |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Hydrogen ion
010405 organic chemistry Chemistry Base free Metals and Alloys chemistry.chemical_element General Chemistry Electron deficiency 010402 general chemistry Photochemistry 01 natural sciences Catalysis Dissociation (chemistry) 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound Hydrolysis Materials Chemistry Ceramics and Composites Hydrogen evolution Boron Borinic acid |
| Zdroj: | Chemical Communications. 55:9821-9824 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c9cc04569d |
| Popis: | A new type of organic proton donor for the strong-acid/base-free hydrogen evolution reaction is reported, by taking advantage of the electron deficiency of the boron center of borinic acid and the strong affinity and hydrolysis reaction between borinic acid and water with hydrogen ion formation. The borinic acid proton donor exhibits even higher current density than H2SO4 to promote hydrogen evolution performance in DMF. |
| Databáze: | OpenAIRE |
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