Development of a Method for the Preparation of Ruthenium Indenylidene-Ether Olefin Metathesis Catalysts
| Autor: | Leonel R. Jimenez, Yann Schrodi, Benjamin J. Gallon, Daniel R. Tolentino |
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| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: |
Magnetic Resonance Spectroscopy
ruthenium alkylidene Phosphines Pharmaceutical Science chemistry.chemical_element Alkenes ring-closing metathesis Triisopropylphosphine Article Catalysis Ruthenium Analytical Chemistry lcsh:QD241-441 chemistry.chemical_compound Ring-closing metathesis lcsh:Organic chemistry Drug Discovery Polymer chemistry Organometallic Compounds Organic chemistry Ring-opening metathesis polymerisation olefin metathesis Physical and Theoretical Chemistry Organic Chemistry Tricyclohexylphosphine ruthenium indenylidene chemistry Chemistry (miscellaneous) Molecular Medicine Phosphine Ethers Acyclic diene metathesis |
| Zdroj: | Molecules, Vol 17, Iss 5, Pp 5675-5689 (2012) Molecules; Volume 17; Issue 5; Pages: 5675-5689 |
| ISSN: | 1420-3049 |
| Popis: | The reactions between several derivatives of 1-(3,5-dimethoxyphenyl)-prop-2-yn-1-ol and different ruthenium starting materials [i.e., RuCl2(PPh3)3 and RuCl2(p-cymene)(L), where L is tricyclohexylphosphine di-t-butylmethylphosphine, dicyclohexylphenylphosphine, triisobutylphosphine, triisopropylphosphine, or tri-n-propylphosphine] are described. Several of these reactions allow for the easy, in-situ and atom-economic preparation of olefin metathesis catalysts. Organic precursor 1-(3,5-dimethoxyphenyl)-1-phenyl-prop-2-yn-1-ol led to the formation of active ruthenium indenylidene-ether complexes, while 1-(3,5-dimethoxyphenyl)-prop-2-yn-1-ol and 1-(3,5-dimethoxyphenyl)-1-methyl-prop-2-yn-1-ol did not. It was also found that a bulky and strong σ-donor phosphine ligand was required to impart good catalytic activity to the new ruthenium complexes. |
| Databáze: | OpenAIRE |
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