Optimum Particle Size of Treated Calcites for CO2 Capture in a Power Plant
| Autor: | M.R. Pérez, José María Fernández Rodríguez, Luis Quesada Carballo, David Cantador Fernández, Álvaro Caballero Amores |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2019 |
| Předmět: |
Materials science
020209 energy Analytical chemistry 02 engineering and technology lcsh:Technology law.invention chemistry.chemical_compound Calcite calcined and rehydrates Adsorption law Greenhouse gas emissions 0202 electrical engineering electronic engineering information engineering calcite calcined and rehydrates General Materials Science Calcination lcsh:Microscopy lcsh:QC120-168.85 Calcite lcsh:QH201-278.5 greenhouse gas emissions lcsh:T carbon dioxide 021001 nanoscience & nanotechnology Co2 adsorption Minimal effect chemistry Carbon dioxide adsorption lcsh:TA1-2040 Particle lcsh:Descriptive and experimental mechanics Particle size lcsh:Electrical engineering. Electronics. Nuclear engineering 0210 nano-technology lcsh:Engineering (General). Civil engineering (General) calcite lcsh:TK1-9971 |
| Zdroj: | Materials, Vol 12, Iss 8, p 1284 (2019) Materials Volume 12 Issue 8 Materials 12(8), 1284 (2019) Helvia. Repositorio Institucional de la Universidad de Córdoba instname |
| ISSN: | 1996-1944 |
| Popis: | This work has analyzed the influence of the particle size of a calcite from a quarry, whether original, calcined, or rehydrated, on the efficiency of CO2 capture of the gases emitted in a coal-fired power plant. Three different particle sizes 0.5 mm, 0.1 mm, and 0.045 mm have been studied. The calcination had a minimal effect on the particle size of the smaller samples A1045 and A1M1 (< 30 &mu m). The N2 isotherms and the CO2 adsorption isotherms at 0 ° C showed a very significant increase in the surface of the calcined and rehydrated samples (A15CH, A1045CH, and A1M1CH) with respect to the calcined or original samples. The results obtained showed that the capture of CO2 for the sample A1M1, with a smaller average particle size (< m, is the most effective. For the sample A1M1 calcined and completely rehydrated (Ca(OH)2), the chemical adsorption of CO2 to form CaCO3 is practically total, under the experimental conditions used (550 ° C and CO2 flow of 20 mL min&minus 1). The weight increase was 34.11% and the adsorption capacity was 577.00 mg g&minus 1. The experiment was repeated 10 times with the same sample A1M1 calcined and rehydrated. No appreciable loss of adsorption capacity was observed. |
| Databáze: | OpenAIRE |
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