Improvement of organic solar cell performance by multiple plasmonic excitations using mixed-silver nanoprisms

Autor: Supeera Nootchanat, Keizo Kato, Sanong Ekgasit, Kazunari Shinbo, Chutiparn Lertvachirapaiboon, Akira Baba, Apichat Phengdaam, Ryousuke Ishikawa
Rok vydání: 2021
Předmět:
Zdroj: Journal of Science: Advanced Materials and Devices, Vol 6, Iss 2, Pp 264-270 (2021)
ISSN: 2468-2179
DOI: 10.1016/j.jsamd.2021.02.007
Popis: Three different silver nanoprisms (AgNPrs) were combined and used as light-trapping materials in organic solar cells (OSCs). These mixed AgNPrs (M-AgNPrs) increased the photocarrier generation in the OSCs due to the broadband absorption, which was attributed to mutual multiple plasmonic excitations covering the entire visible light region. The M-AgNPrs were incorporated into a poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) hole-transport layer in the OSCs. The UV–vis spectra, atomic force microscope images and current density versus voltage curves of the fabricated devices were recorded at different loading concentrations of the M-AgNPrs. Finite-difference time-domain simulation, impedance spectroscopy, and measurement of incident photon-to-current efficiency of the devices confirmed the effect of the multiple plasmonic excitations. The results suggest that, in an optimum condition, the efficiency of the OSCs loaded with M-AgNPrs was 7.9% higher than the reference OSC.
Databáze: OpenAIRE