On the Crystallography and Thermodynamics in Orientationally Disordered Phases in Two-Component Systems
| Autor: | J. Ll. Tamarit, Harry A.J. Oonk, Josep Salud, Yvette Haget, David López, Maria Barrio, Philippe Négrier |
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| Rok vydání: | 1997 |
| Předmět: |
Enthalpy
Intermolecular force Thermodynamics Crystal structure Condensed Matter Physics Electronic Optical and Magnetic Materials Inorganic Chemistry chemistry.chemical_compound Crystallography chemistry Materials Chemistry Ceramics and Composites Hydroxymethyl Physical and Theoretical Chemistry Thermal analysis Powder diffraction Phase diagram Entropy (order and disorder) |
| Zdroj: | Journal of Solid State Chemistry. 133:536-544 |
| ISSN: | 0022-4596 |
| DOI: | 10.1006/jssc.1997.7530 |
| Popis: | The experimental two-component phase diagram between the orientationally disordered crystals 2-amino-2-methyl-1,3-propanediol (AMP) and 1,1,1-tris(hydroxymethyl)propane (PG) has been established from room temperature to the liquid state using thermal analysis and X-ray powder diffraction techniques. The intermolecular interactions in the orientationally disordered mixed crystals of the mentioned system and other related two-component systems are discussed by analyzing the evolution of the packing coefficient as a function of the the composition. A thermodynamic analysis of the presented phase diagram and the redetermined AMP/NPG (2,2-dimethyl-1,3-propanediol) is reported on the basis of the enthalpy–entropy compensation theory. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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