Lewis acid catalysis: catalytic hydroboration of alkynes initiated by Piers' borane
| Autor: | Frank Glorius, Thorsten vom Stein, Douglas W. Stephan, Mirco Fleige, Juri Möbus |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
010405 organic chemistry
Pinacol Metals and Alloys General Chemistry Borane 010402 general chemistry 01 natural sciences Medicinal chemistry Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Lewis acid catalysis chemistry.chemical_compound Hydroboration chemistry Materials Chemistry Ceramics and Composites Organic chemistry |
| Zdroj: | Chemical Communications. 52:10830-10833 |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | Terminal and internal alkynes are efficiently hydroborated to (E)-alkenyl pinacol boronic esters with excellent yields and selectivities using Piers' borane, (HB(C6F5)2) as a pre-catalyst for the dissymmetrically gem-diborylated catalyst of the form RCH2CR′(Bpin)(B(C6F5)2). |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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