Infrared Laser Spectroscopy of Imidazole Complexes in Helium Nanodroplets: Monomer, Dimer, and Binary Water Complexes
| Autor: | Myong Yong Choi, Roger E. Miller |
|---|---|
| Rok vydání: | 2006 |
| Předmět: |
Nanotubes
Spectrophotometry Infrared Macromolecular Substances Lasers Dimer Transition dipole moment Far-infrared laser Imidazoles Water Binary number chemistry.chemical_element Photochemistry Helium chemistry.chemical_compound chemistry Ab initio quantum chemistry methods Quantum Theory Physical chemistry Imidazole Physical and Theoretical Chemistry Spectroscopy Dimerization |
| Zdroj: | The Journal of Physical Chemistry A. 110:9344-9351 |
| ISSN: | 1520-5215 1089-5639 |
| DOI: | 10.1021/jp0624146 |
| Popis: | Infrared laser spectroscopy has been used to characterize imidazole (IM), imidazole dimer (IMD), and imidazole-water (IMW) binary systems formed in helium nanodroplets. The experimental results are compared with ab initio calculations reported here. Vibrational transition moment angles provide conclusive assignments for the various complexes studied here, including IM, one isomer of IMD, and two isomers of the IMW binary complexes. |
| Databáze: | OpenAIRE |
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