Low Cost Filled Thermostable Ionomer Membrane for P.E.M.F.C

Autor:	C. Poinsignon, I. Amodio, J.Y. Sanchez, D. Foscallo
Rok vydání:	1998
Předmět:	Cationic exchange chemistry.chemical_compound Membrane Materials science Chemical engineering chemistry Charge carrier Relative humidity Polysulfone Conductivity Composite material Ionomer
Zdroj:	Scopus-Elsevier
ISSN:	1946-4274 0272-9172
DOI:	10.1557/proc-548-307
Popis:	A filled ionomeric membrane was achieved by dispersing phosphatoantimonic acid H3Sb3P2014, ×H20 (H3) in a Sulfonated PolySulfone (SPS) solution [1]. Water up-take is higher for filled than unfilled membrane as well as Protonic conductivity which is larger than that expected from the overall calculated concentration in charge carriers : a conductivity value of 0.135 S.cm−1 was gained at 50°C under 1003% Relative Humidity (HR) for a 1.6 meq.g−1 cationic exchange capacity (cec) SPS filled with 8% in H3 against 0.06S.cm−1 for an unfilled one. Mechanical measurements on the wet membrane shows the plasticizing effect of sulfonation, water and of the filler content which simultanously reinforced the cohesion of the membrane.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e6508ad2d4207e67e2b79ab4c8903d54 https://doi.org/10.1557/proc-548-307 Zobrazit plný text záznamu Full text from SpringerLink