Opportunities and Challenges for Organic Electrodes in Electrochemical Energy Storage
| Autor: | Philippe Poizot, Joël Gaubicher, Yanliang Liang, Lionel Dubois, Stéven Renault, Yan Yao |
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| Přispěvatelé: | Institut des Matériaux Jean Rouxel (IMN), Université de Nantes - UFR des Sciences et des Techniques (UN UFR ST), Université de Nantes (UN)-Université de Nantes (UN)-Ecole Polytechnique de l'Université de Nantes (EPUN), Université de Nantes (UN)-Université de Nantes (UN)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Conception d’Architectures Moléculaires et Processus Electroniques (CAMPE ), SYstèmes Moléculaires et nanoMatériaux pour l’Energie et la Santé (SYMMES), Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche Interdisciplinaire de Grenoble (IRIG), Direction de Recherche Fondamentale (CEA) (DRF (CEA)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Direction de Recherche Fondamentale (CEA) (DRF (CEA)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Grenoble Alpes (UGA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche Interdisciplinaire de Grenoble (IRIG), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Grenoble Alpes (UGA), Département Interfaces pour l'énergie, la Santé et l'Environnement (DIESE), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA), Department of Electrical and Computer Engineering [Houston], University of Houston, Université de Nantes (UN)-Université de Nantes (UN)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Ecole Polytechnique de l'Université de Nantes (EPUN), Université de Nantes (UN)-Université de Nantes (UN) |
| Rok vydání: | 2020 |
| Předmět: |
Battery (electricity)
Metrics & More Article Recommendations Beyond Li Battery Chemistry XXXX 010405 organic chemistry Chemistry Nanotechnology Organic radical battery XXX General Chemistry Electrolyte 010402 general chemistry 01 natural sciences 7. Clean energy Energy storage 0104 chemical sciences 12. Responsible consumption 13. Climate action XXX−XXX Organic Batteries AE 75 7.2. Nonaqueous Multivalent Metal−Organic 8.2. Hybrid Organic−Inorganic Batteries AN 84 8.2.1. Aqueous Lithium-Ion Batteries (ALIBs) AN 85 8.2.2. Aqueous Sodium-Ion Batteries (ASIBs) AN 86 8.2.3. Aqueous Potassium-Ion Batteries 87 Electrode [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci] Specific energy Electronics Electrochemical energy storage |
| Zdroj: | Chemical Reviews Chemical Reviews, 2020, 120, pp.6490-6557. ⟨10.1021/acs.chemrev.9b00482⟩ Chemical Reviews, American Chemical Society, 2020, 120, pp.6490-6557. ⟨10.1021/acs.chemrev.9b00482⟩ |
| ISSN: | 1520-6890 0009-2665 |
| Popis: | International audience; As the world moves toward electromobility and a concomitant decarbonization of its electrical supply, modern society is also entering a so-called fourth industrial revolution marked by a boom of electronic devices and digital technologies. Consequently, battery demand has exploded along with the need for ores and metals to fabricate them. Starting from such a critical analysis and integrating robust structural data, this review aims at pointing out there is room to promote organic-based electrochemical energy storage. Combined with recycling solutions, redox-active organic species could decrease the pressure on inorganic compounds and offer valid options in terms of environmental footprint and possible disruptive chemistries to meet the energy storage needs of both today and tomorrow. We review state-of-the-art developments in organic batteries, current challenges, and prospects, and we discuss the fundamental principles that govern the reversible chemistry of organic structures. We provide a comprehensive overview of all reported cell configurations that involve electroactive organic compounds working either in the solid state or in solution for aqueous or nonaqueous electrolytes. These configurations include alkali (Li/Na/K) and multivalent (Mg, Zn)-based electrolytes for conventional "sealed" batteries and redox-flow systems. We also highlight the most promising systems based on such various chemistries relying on appropriate metrics such as operation voltage, specific capacity, specific energy, or cycle life to assess the performances of electrodes. |
| Databáze: | OpenAIRE |
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