Selective hydroboration of electron-rich isocyanates by an NHC-copper(I) alkoxide

Autor: Laura E. English, Thomas M. Horsley Downie, Catherine L. Lyall, Mary F. Mahon, Claire L. McMullin, Samuel E. Neale, Carla M. Saunders, David J. Liptrot
Rok vydání: 2023
Předmět:
Zdroj: Chemical communications (Cambridge, England).
ISSN: 1364-548X
Popis: The (IPr)CuOtBu catalysed reduction of 11 aryl and alkyl isocyanates with pinacolborane gave only the boraformamides, pinBN(R)C(O)H, in the case of electron rich isocyanates. A computational study provided insight into this selectivity.
Databáze: OpenAIRE