| Popis: |
Infrared spectra of M(1,10-diaminodecane)Ni(CN)(4)center dot,1,5 G ( M=Co, Ni or Cd; G=o-xylene, m-xylene, p-xylene) and Cd(1,6-diaminohexane)M(CN)(4)center dot C6H6 ( M=Cd or Hg) clathrates are reported. The 1,10-diaminodecane and 1,6-diaminohexane molecules in the host permit the inclusion of bulky guest molecules. The spectral data of clathrates were compared with those of the corresponding host. The spectral features suggest that these compounds are similar in structure to other Hofmann-type and Hofmann-T-d type clathrates, respectively. |
