Preparation and physical properties of polypyrrole/zeolite composites
| Autor: | Hussein Baqiah, Emma Ziezie Mohd Tarmizi, Halimah Mohamed Kamari, Zainal Abidin Talib |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: |
Thermogravimetric analysis
Materials science General Physics and Astronomy 02 engineering and technology Conductivity 010402 general chemistry 021001 nanoscience & nanotechnology Polypyrrole 01 natural sciences lcsh:QC1-999 0104 chemical sciences Amorphous solid chemistry.chemical_compound Van der Pauw method chemistry Thermal stability Fourier transform infrared spectroscopy Composite material 0210 nano-technology Zeolite lcsh:Physics |
| Zdroj: | Results in Physics, Vol 11, Iss, Pp 793-800 (2018) |
| ISSN: | 2211-3797 |
| Popis: | Polypyrrole (PPy′)/zeolite composites were synthesized via chemical oxidation of pyrrole in the presence of zeolite. FeCl3 was used as an oxidant with the FeCl3-to-pyrrole molar ratio (MR) equal to 1. The zeolite contents were 0%, 5%, 10%, 15% and 20% of the total weight of PPy′. For comparison, pure PPy″ with FeCl3–pyrrole MR equal to 2 was also synthesized using the same method. The structural and physical properties of the samples were studied using X-rays diffraction (XRD), Fourier transform infrared spectroscopy, field emission electron scanning microscopy, thermogravimetric analysis, van Der Pauw technique and UV–VIS-NIR spectroscopy. The XRD of PPy′/zeolite (5%) revealed a presence of crystalline nature of zeolite in a spectrum of host amorphous PPy′. The XRD peaks increased, became stronger and shifted slightly to higher 2θ in PPy′/zeolite (10–20%) composites. Compared with PPy′, the composites were denser, more compact and had better thermal stability. The composites conductivity increased while their bandgap tended to reduce with increasing of zeolite. PPy′/zeolite (20%) composite had the highest conductivity value of 3.6 S cm−1 with an optical bandgap of 2.21 eV. The results showed that zeolite has been incorporated into PPy′ matrix and improved its physical properties. Keywords: Polypyrrole composites, Band gap, Conductivity, Thermal stability, Zeolite |
| Databáze: | OpenAIRE |
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