Nitro-tetrazole based high performing explosives: Recent overview of synthesis and energetic properties
| Autor: | Qamar-un-nisa Tariq, Xin Yin, Jian-Guo Zhang, Saira Manzoor |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
0209 industrial biotechnology
Materials science Explosive material Computational Mechanics 02 engineering and technology 01 natural sciences 010305 fluids & plasmas Preparation method chemistry.chemical_compound 020901 industrial engineering & automation 0103 physical sciences Tetrazole chemistry.chemical_classification Mechanical Engineering Detonation velocity Heterocyclic Metals and Alloys Energetic materials Combinatorial chemistry Standard enthalpy of formation Improved performance Military Science chemistry High-performing explosives Functional groups Ceramics and Composites Nitro Azole |
| Zdroj: | Defence Technology, Vol 17, Iss 6, Pp 1995-2010 (2021) |
| ISSN: | 2214-9147 |
| DOI: | 10.1016/j.dt.2021.02.002 |
| Popis: | Heterocyclic skeleton (Azoles) and different energetic groups containing high performing explosives are highly emerged in recent years to meet the challenging requirements of energetic materials in both military and civilian applications with improved performance. For this purpose tetrazole (Azole) is identified as an attractive heterocyclic backbone with energetic functional groups nitro (-NO2), nitrato (-ONO2), nitrimino (-NNO2), and nitramino (–NH–NO2) to replace the traditionally used high performing explosives. The tetrazole based compounds having these energetic functional groups demonstrated advanced energetic performance (detonation velocity and pressure), densities, and heat of formation (HOF) and became a potential replacement of traditional energetic compounds such as RDX. This review presents a summary of the recently reported nitro-tetrazole energetic compounds containing poly-nitro, di/mono-nitro, nitrato/nitramino/nitrimino, bridged/bis/di tetrazole and nitro functional groups, describing their preparation methods, advance energetic properties, and further applications as high-performing explosives, especially those reported in the last decade. This review aims to provide a fresh concept for designing nitro-tetrazole based high performing explosives together with major challenges and perspectives. |
| Databáze: | OpenAIRE |
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