All-in-One Graphene Based Composite Fiber: Toward Wearable Supercapacitor

Autor: Ricky Tjandra, Zhongwei Chen, Wenwen Liu, Lucas Lim, Aiping Yu, Yangshuai Liu, Lathankan Rasenthiram
Rok vydání: 2017
Předmět:
Zdroj: ACS Applied Materials & Interfaces. 9:39576-39583
ISSN: 1944-8252
1944-8244
DOI: 10.1021/acsami.7b10182
Popis: Graphene fibers (GF) have aroused great interest in wearable electronics applications because of their excellent mechanical flexibility and superior electrical conductivity. Herein, an all-in-one graphene and MnO2 composite hybrid supercapacitor fiber device has been developed. The unique coaxial design of this device facilitates large-scale production while avoiding the risk of short circuiting. The core backbone of the device consists of GF that not only provides mechanical stability but also ensures fast electron transfer during charge–discharge. The introduction of a MnO2 (200 nm in length) hierarchical nanostructured film enhanced the pseudocapacitance dramatically compared to the graphene-only device in part because of the abundant number of active sites in contact with the poly(vinyl alcohol) (PVA)/H3PO4 electrolyte. The entire device exhibits outstanding mechanical strength as well as good electrocapacitive performance with a volumetric capacitance of 29.6 F cm–3 at 2 mv s–1. The capacitance of th...
Databáze: OpenAIRE