Kinetic degradation of amoxicillin by using the electro-Fenton process in the presence of a graphite rods from used batteries

Autor: Zehira Garti, Abdeltif Amrane, Farida Aissani-Benissad, Hakima Kadji, Idris Yahiaoui
Přispěvatelé: Université Abderrahmane Mira [Béjaïa], Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Université de Rennes (UNIV-RENNES)-Institut National des Sciences Appliquées (INSA)
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Chinese Journal of Chemical Engineering
Chinese Journal of Chemical Engineering, 2021, 32, pp.183-190. ⟨10.1016/j.cjche.2020.08.032⟩
Chinese Journal of Chemical Engineering, Elsevier, 2021, 32, pp.183-190. ⟨10.1016/j.cjche.2020.08.032⟩
ISSN: 1004-9541
DOI: 10.1016/j.cjche.2020.08.032⟩
Popis: International audience; This study reports the removal of amoxicillin (AMX) in aqueous media using the electro-Fenton process in the presence of a graphite cathode recovered from used batteries. The impact of the relevant parameters on the electro-Fenton process, namely the applied current intensity, the temperature, the initial concentration of AMX and the initial concentration of ferrous ions were investigated. The results showed that the optimal values were: I= 600 mA, T= 25°C, [AMX] 0 = 0.082 mmol•L −1 and [Fe 2+ ]= 1 mmol•L −1 , leading to 95% degradation and 74% mineralization. The model parameters of AMX mineralization were determined using nonlinear methods, showing that it follows a pseudo-second-order kinetic. The Energy consumption (EC) calculated under the optimal values was found to be 0.79 kW•h −1 •g −1 , which was of the same order of magnitude of those reported in other findings; while it is noteworthy that the electrodes used in our study are of a lower cost.
Databáze: OpenAIRE