catena-Poly[[manganese(III)-bis{μ-2-[(2-hydroxyethyl)iminomethyl]-6-methoxyphenolato-κ3 O 1,N:O 2;κ3 O 2:N,O 1}] iodide]
| Autor: | Oleg M. Stetsyuk, Svitlana R. Petrusenko, Irina V. Omelchenko |
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| Jazyk: | angličtina |
| Rok vydání: | 2013 |
| Předmět: |
chemistry.chemical_classification
Metal-Organic Papers Hydrogen bond Coordination polymer Metal ions in aqueous solution Iodide chemistry.chemical_element General Chemistry Meth Manganese Condensed Matter Physics Bioinformatics Medicinal chemistry chemistry.chemical_compound chemistry General Materials Science |
| Zdroj: | Acta Crystallographica Section E: Structure Reports |
| ISSN: | 1600-5368 |
| Popis: | In the title one-dimensional coordination polymer, {[Mn(C10H12NO3)2]I} n , the potentially tetra-dentate (O,O,O,N) 2-[(2-hy-droxy-eth-yl)imino-meth-yl]-6-meth-oxy-phenol (H2 L) ligands are mono-deprotonated (as HL (-)) and coordinated by the metal ions in a tridentate chelate-bridging fashion [2.0111112]. The Mn(III) atom possesses a distorted trans-MnO4N2 octa-hedral coordination environment. The bridging ligands lead to [010]-chain polymeric cations {[Mn(HL)2](+)} n in the crystal. The charge-balancing iodide ions are disordered over two sites in a 0.690 (2):0.310 (2) ratio and a weak O-H⋯I hydrogen bond occurs. The crystal studied was found to be a racemic twin. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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