Total synthesis of lycorine-type alkaloids by cyclopropyl ring-opening rearrangement
| Autor: | Fan Li, Jingbo Chen, Hongbin Zhang, Jianping Liu, Annan Zhao, Long Ai, Dandan Liu |
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| Rok vydání: | 2014 |
| Předmět: |
Chemistry
Stereochemistry Proton Magnetic Resonance Spectroscopy Organic Chemistry Total synthesis Crystallography X-Ray Ring (chemistry) Lycorine Biochemistry Phenanthridines chemistry.chemical_compound Alkaloids Cyclization Amaryllidaceae Alkaloids Carbon-13 Magnetic Resonance Spectroscopy Physical and Theoretical Chemistry |
| Zdroj: | Org. Biomol. Chem.. 12:3191-3200 |
| ISSN: | 1477-0539 1477-0520 |
| Popis: | A practical method for the synthesis of lycorine-type alkaloids with cis-B/C ring structure has been developed. Based on the reactions of aminocyclization, palladium-mediated arylation and especially cyclopropyl ring-opening rearrangement, the synthesis of anhydrocaranine, (±)-γ-lycorane and putative (±)-amarbellisine was accomplished. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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