Iron-Catalyzed Aromatic Amination for Nonsymmetrical Triarylamine Synthesis

Autor:	Ryuji Imayoshi, Takuji Hatakeyama, Kazuhiro Norisuye, Hikaru Takaya, Masayoshi Jin, Yuya Yoshimoto, Yoshiki Sohrin, Masaharu Nakamura, Sujit K. Ghorai
Rok vydání:	2012
Předmět:	Magnesium Iron Aryl Iron catalyzed chemistry.chemical_element Halide General Chemistry Biochemistry Catalysis chemistry.chemical_compound Colloid and Surface Chemistry chemistry Yield (chemistry) Organic chemistry Lithium Amines Amination Electronic materials
Zdroj:	Journal of the American Chemical Society. 134:20262-20265
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja309845k
Popis:	Novel iron-catalyzed amination reactions of various aryl bromides have been developed for the synthesis of diaryl- and triarylamines. The key to the success of this protocol is the use of in situ generated magnesium amides in the presence of a lithium halide, which dramatically increases the product yield. The present method is simple and free of precious and expensive metals and ligands, thus providing a facile route to triarylamines, a recurrent core unit in organic electronic materials as well as pharmaceuticals.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e4dc50c973e119bbfe683f028ae4d8a6 https://doi.org/10.1021/ja309845k Zobrazit plný text záznamu