Synthesis of Type II Ge and Ge–Si Alloyed Clathrates Using Solid-State Electrochemical Oxidation of Zintl Phase Precursors

Autor:	Andrew Dopilka, Alexander Ovchinnikov, Amanda Childs, Svilen Bobev, Xihong Peng, Candace K. Chan
Rok vydání:	2022
Předmět:	Inorganic Chemistry Physical and Theoretical Chemistry
Zdroj:	Inorganic Chemistry. 61:12363-12372
ISSN:	1520-510X 0020-1669
DOI:	10.1021/acs.inorgchem.2c01748
Popis:	Germanium clathrates with the type II structure are open-framework materials that show promise for various applications, but the difficulty of achieving phase-pure products via traditional synthesis routes has hindered their development. Herein, we demonstrate the synthesis of type II Ge clathrates in a two-electrode electrochemical cell using Na
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e45faefd484000781063d971efd5899c https://doi.org/10.1021/acs.inorgchem.2c01748 Zobrazit plný text záznamu