Kinetics and mechanism of polysulfides formation by a reaction between hydrogen sulfide and orthorhombic cyclooctasulfur
Autor: | Alexey Kamyshny, Tamir Buchshtav, Khoren Avetisyan |
---|---|
Rok vydání: | 2019 |
Předmět: |
010504 meteorology & atmospheric sciences
Cyclooctasulfur Hydrogen sulfide Batch reactor Kinetics Inorganic chemistry 010502 geochemistry & geophysics 01 natural sciences 6. Clean water Reaction rate chemistry.chemical_compound chemistry Geochemistry and Petrology Orthorhombic crystal system Polysulfide 0105 earth and related environmental sciences |
Zdroj: | Geochimica et Cosmochimica Acta, 247 . pp. 96-105. |
ISSN: | 0016-7037 |
Popis: | A detailed study of kinetics of reaction between hydrogen sulfide and orthorhombic cyclooctasulfur at environmentally relevant conditions, which results in formation of inorganic polysulfides, was performed. Rates of reaction were measured as a function of pH, temperature and concentrations of S2− and S0 in airtight stirred batch reactor. Reaction was carried out at [S0]/[S2−] |
Databáze: | OpenAIRE |
Externí odkaz: |