Poly[di-μ3-chlorido-[μ2-(3-pyridyl)(4-pyridyl)methanone-κ2N:N′]dicopper(I)]

Autor: Jennifer L. Hittle, Robert L. LaDuca
Rok vydání: 2008
Předmět:
Zdroj: Acta Crystallographica Section E: Structure Reports
ISSN: 1600-5368
DOI: 10.1107/s1600536808038385
Popis: In the title compound, [Cu(2)Cl(2)(C(11)H(8)N(2)O)](n), stair-like ribbons of formula [Cu(2)Cl(2)](n) are linked into coordination polymer layers by tethering (3-pyrid-yl)(4-pyrid-yl)methanone (3,4'-dpk) ligands. The two distinct Cu(I) centres both adopt distorted CuNCl(3) tetra-hedral coordinations. Individual [Cu(2)Cl(2)(3,4'-dpk)](n) layers stack in an AB pattern along the c direction by way of weak C-H⋯O inter-actions between the pyridyl rings and ketone O atoms.
Databáze: OpenAIRE