Poly[di-μ3-chlorido-[μ2-(3-pyridyl)(4-pyridyl)methanone-κ2N:N′]dicopper(I)]
Autor: | Jennifer L. Hittle, Robert L. LaDuca |
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Rok vydání: | 2008 |
Předmět: | |
Zdroj: | Acta Crystallographica Section E: Structure Reports |
ISSN: | 1600-5368 |
DOI: | 10.1107/s1600536808038385 |
Popis: | In the title compound, [Cu(2)Cl(2)(C(11)H(8)N(2)O)](n), stair-like ribbons of formula [Cu(2)Cl(2)](n) are linked into coordination polymer layers by tethering (3-pyrid-yl)(4-pyrid-yl)methanone (3,4'-dpk) ligands. The two distinct Cu(I) centres both adopt distorted CuNCl(3) tetra-hedral coordinations. Individual [Cu(2)Cl(2)(3,4'-dpk)](n) layers stack in an AB pattern along the c direction by way of weak C-H⋯O inter-actions between the pyridyl rings and ketone O atoms. |
Databáze: | OpenAIRE |
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