Ruthenium-catalyzed cross-dehydrogenative ortho-N-carbazolation of diarylamines: versatile access to unsymmetrical diamines

Autor:	Marie-Laure Louillat, Fabien Legros, Frederic W. Patureau, Agostino Biafora
Rok vydání:	2013
Předmět:	Ortho position integumentary system organic chemicals Intermolecular force chemistry.chemical_element General Chemistry Combinatorial chemistry Catalysis Ruthenium chemistry.chemical_compound chemistry Organic chemistry Organic synthesis
Zdroj:	Angewandte Chemie (International ed. in English). 53(13)
ISSN:	1521-3773
Popis:	The dehydrogenative C–N cross-coupling of unprotected, secondary anilines through ortho-N-carbazolation has been achieved using a Ru catalytic system with O2 as the terminal oxidant. The reactions proceed in an intermolecular fashion, selectively in the ortho position. Implications for the field of organic synthesis are discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e3a3c6002265b2e52f3c20a006760778 https://pubmed.ncbi.nlm.nih.gov/24554560 Zobrazit plný text záznamu Plný text