Autor:	Ken D. Shimizu, Roger D. Rasberry, Brent E. Dial, Perry J. Pellechia, Salvatore Profeta, Mark D. Smith, Brooke N. Bullock
Rok vydání:	2010
Předmět:	Crystallography Chemistry Rotor (electric) law Computational chemistry Organic Chemistry macromolecular substances Molecular rotors Physical and Theoretical Chemistry Rotation Biochemistry law.invention
Zdroj:	Organic Letters. 13:244-247
ISSN:	1523-7052 1523-7060
Popis:	A molecular rotor was designed in which the rate of rotation is accelerated by guest complexation. The binding of an acetate guest to the urea groups lowers the barrier of the adjacent C(aryl)-N(imide) bond by 2 to 4 kcal/mol. This behavior is in contrast to most molecular rotors in which guest complexation slows rotation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e356943ff63032796ce46386f9260e4a https://doi.org/10.1021/ol102659n Zobrazit plný text záznamu