Dependence on the crystallographic orientation of Au for the potential window of the electrical double-layer region in imidazolium-based ionic liquids
| Autor: | Hiroyuki Ueda, Soichiro Yoshimoto, Ryuichi Tsuji, Katsuhiko Nishiyama, Ryo Taguchi |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: |
chemistry.chemical_classification
Au single crystal electrochemistry Substrate (electronics) Electrochemistry cyclic voltammetry lcsh:Chemistry Crystallography chemistry.chemical_compound chemistry lcsh:Industrial electrochemistry lcsh:QD1-999 Ionic liquid Electrode Cyclic voltammetry Single crystal Alkyl ionic liquid Electrochemical window lcsh:TP250-261 |
| Zdroj: | Electrochemistry Communications, Vol 20, Iss, Pp 26-28 (2012) |
| ISSN: | 1388-2481 |
| Popis: | The influence of the alkyl chain length of the bis(trifluoromethylsulfonyl)imide-based ionic liquids 1-ethyl-3-methylimidazolium, 1-butyl-3-methylimidazolium, 1-hexyl-3-methylimidazolium, 1-methyl-3-octylimidazolium, and 1-decyl-3-methylimidazolium cation on the potential window was investigated with low-index Au single crystal electrodes by cyclic voltammetry. The potential window of the electrical double-layer region was found to depend on the crystallographic orientation of Au, which indicated a difference in the strength of cation adsorption on the Au substrate. The potential window of the electrical double-layer region was also dependent upon the alkyl chain length of the imidazolium cation. Keywords: Ionic liquid, Au single crystal electrochemistry, Cyclic voltammetry |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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