Iron-Based Catalytically Active Complexes in Preparation of Functional Materials
| Autor: | Pawel Bloniarz, Andrzej Sobkowiak, Katarzyna Rydel-Ciszek, Izabela Zaborniak, Karolina Surmacz, Paweł Chmielarz, Tomasz Pacześniak |
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| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
Abundance (chemistry)
Radical polymerization Bioengineering Homogeneous catalysis 010402 general chemistry Heterogeneous catalysis lcsh:Chemical technology 01 natural sciences Redox Catalysis “green” oxidants lcsh:Chemistry Transition metal Chemical Engineering (miscellaneous) Molecule lcsh:TP1-1185 010405 organic chemistry Chemistry Process Chemistry and Technology oxidation processes Combinatorial chemistry homogeneous catalysis 0104 chemical sciences heterogeneous catalysis lcsh:QD1-999 controlled radical polymerization iron-based catalysts |
| Zdroj: | Processes, Vol 8, Iss 1683, p 1683 (2020) |
| ISSN: | 2227-9717 |
| Popis: | Iron complexes are particularly interesting as catalyst systems over the other transition metals (including noble metals) due to iron’s high natural abundance and mediation in important biological processes, therefore making them non-toxic, cost-effective, and biocompatible. Both homogeneous and heterogeneous catalysis mediated by iron as a transition metal have found applications in many industries, including oxidation, C-C bond formation, hydrocarboxylation and dehydration, hydrogenation and reduction reactions of low molecular weight molecules. These processes provided substrates for industrial-scale use, e.g., switchable materials, sustainable and scalable energy storage technologies, drugs for the treatment of cancer, and high molecular weight polymer materials with a predetermined structure through controlled radical polymerization techniques. This review provides a detailed statement of the utilization of homogeneous and heterogeneous iron-based catalysts for the synthesis of both low and high molecular weight molecules with versatile use, focusing on receiving functional materials with high potential for industrial application. |
| Databáze: | OpenAIRE |
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