Hypervalent iodine reagent-mediated reactions involving rearrangement processes
| Autor: | Boying Guo, Xiaoxian Li, Beibei Zhang, Yunfei Du |
|---|---|
| Rok vydání: | 2020 |
| Předmět: |
Chemistry
Metals and Alloys Hypervalent molecule chemistry.chemical_element General Chemistry Iodine Medicinal chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Cyclopropane chemistry.chemical_compound Organic reaction Reagent Beckmann rearrangement Materials Chemistry Ceramics and Composites Oxidative coupling of methane Hofmann rearrangement |
| Zdroj: | Chemical communications (Cambridge, England). 56(91) |
| ISSN: | 1364-548X |
| Popis: | Hypervalent iodine reagents have been extensively employed in various types of oxidative organic reactions including oxidative coupling/cyclization, bifunctionalization of olefins and cyclopropane, C-H functionalization, and oxidative rearrangement reactions. In this review, the developments of the exclusive hypervalent iodine-mediated reactions involving oxidative rearrangement processes, including [1,2]-migration, Hofmann rearrangement, Beckmann rearrangement, ring contraction, ring expansion, [3,3]-sigmatropic/iodonium-Claisen rearrangement and some miscellaneous rearrangements, have been summarized. |
| Databáze: | OpenAIRE |
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