Anomalous Diffusion With an Apparently Negative Diffusion Coefficient in a One-Dimensional Quantum Molecular Chain Model

Autor: Satoshi Tanaka, Kazuki Kanki, Tomio Petrosky, Sho Nakade
Rok vydání: 2021
Předmět:
Zdroj: Symmetry
Volume 13
Issue 3
Symmetry, Vol 13, Iss 506, p 506 (2021)
DOI: 10.20944/preprints202102.0131.v1
Popis: An interesting anomaly of the diffusion process with an apparently negative diffusion coefficient defined through the mean-square displacement in a one-dimensional quantum molecular chain model is shown. Nevertheless, the system satisfies the H-theorem, so that the second law of thermodynamics is satisfied. The reason why the “diffusion constant” becomes negative is due to the effect of the phase mixing process, which is a characteristic result of the one-dimensionality of the system. We illustrate the situation where this negative “diffusion constant” appears.
Databáze: OpenAIRE