Expedient routes to 4,4-dialkyl- 5-methylene-1,3-oxazolines
| Autor: | Elena Yu. Schmidt, A. V. Afonin, L. V. Klyba, Alexander M. Vasil'tsov, Al'bina I. Mikhaleva, D.‐S. D. Toryashinova, Jan-Dirk Arndt, Jochem Henkelmann, Alexey B. Zaitsev |
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| Jazyk: | angličtina |
| Rok vydání: | 2003 |
| Předmět: | |
| Zdroj: | ARKIVOC, Vol 2003, Iss 13, Pp 35-44 (2003) |
| ISSN: | 1551-7012 1551-7004 |
| Popis: | Tertiary alkynols with benzonitrile cyclize in the presence of acids to give 4,4-dialkyl-5methylene-2-phenyl-1,3-oxazolines. Aliphatic nitriles and tertiary acetylenic alcohols are transformed, through intermediate acetylenic amides, which undergo ring-closure upon heating with solid alkali, to 2-alkyl-4,4-dialkyl-5-methylene-1,3-oxazolines. |
| Databáze: | OpenAIRE |
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