Electrooxidation of phenol on different organo bentonite-based electrodes
Autor: | M. Žunić, N. Jović-Jovičić, Dušan Jovanović, Aleksandra Milutinović-Nikolić, A. Abu Rabi-Stanković, Zorica Mojović, Predrag Banković |
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Rok vydání: | 2011 |
Předmět: |
Tetramethylammonium
Tafel equation Phenol Electrooxidation Inorganic chemistry Geology 02 engineering and technology Organo bentonite 010402 general chemistry 021001 nanoscience & nanotechnology Electrochemistry 01 natural sciences 0104 chemical sciences chemistry.chemical_compound chemistry Physisorption Geochemistry and Petrology Electrode Bentonite Clay-modified electrode Cyclic voltammetry 0210 nano-technology |
Zdroj: | Applied Clay Science |
ISSN: | 0169-1317 |
DOI: | 10.1016/j.clay.2010.12.008 |
Popis: | Bentonite was modified by the exchange of inorganic cations with hexadecyl trimethylammonium, dodecyl trimethylammonium or tetramethylammonium cation. The obtained materials were characterized by physisorption of nitrogen and X-ray diffraction analysis. Multisweep cyclic voltammetry was applied to analyze phenol response on different organo bentonite-based electrodes. The aim of the investigation was to determine the influence of the type of modifying agent on the electrochemical performance of the investigated electrodes. All electrodes exhibited similar electrochemical behavior but with different intensities of the electrochemical response and Tafel slopes. The difference in Tafel slopes reflected different level of involvement of pores in the phenol electrooxidation. |
Databáze: | OpenAIRE |
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