Atomic Vibrations in Glasses
| Autor: | Benoit Ruffle, Bernard Hehlen |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Amorphous silicon
Vibrational density Materials science Condensed matter physics Infrared spectroscopy FOS: Physical sciences Disordered Systems and Neural Networks (cond-mat.dis-nn) Condensed Matter - Disordered Systems and Neural Networks Condensed Matter::Disordered Systems and Neural Networks Vibration chemistry.chemical_compound Thermal conductivity chemistry Boron oxide Molecule Boson peak |
| Zdroj: | Encyclopedia of Glass Science, Technology, History, and Culture |
| DOI: | 10.48550/arxiv.1908.08321 |
| Popis: | In glasses, atomic disorder combined with atomic connectivity makes understanding of the nature of the vibrations much more complex than in crystals or molecules. With a simple model, however, it is possible to show how disorder generates quasi-local modes on optic branches as well as on acoustic branches at low-frequency. The latter modes, possibly hybridizing with low-lying optic modes in real glasses, lead to the excess, low-frequency excitations known as {\it boson-peak modes}, which are lacking in crystals. The spatially quasi-localized vibrations also explain anomalies in thermal conductivity and the end of the acoustic branches, two other specific features of glasses. Together with the quasi-localization of the modes at the nanometric scale, structural disorder lifts the crystalline or molecular spectroscopic selection rules and makes interpretation of experiments difficult. Nevertheless, vibrations in simple glasses such as vitreous silica or vitreous boron oxide are nowadays rather well described. But a comprehensive understanding of the boson peak modes remains a highly debated issue as illustrated by three archetypal glass systems, vitreous SiO$_2$ and B$_2$O$_3$ and amorphous silicon. Comment: To be published in "Encyclopedia of Glass", Ed. P. Richet |
| Databáze: | OpenAIRE |
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