Inductive effect of template containing UTD-1 seeds on the synthesis of zeolite SSZ-24
| Autor: | Henri Kessler, J.-L. Paillaud, Valentin Valtchev, E.J. Creyghton |
|---|---|
| Přispěvatelé: | Laboratoire de Matériaux Minéraux (LMM), Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Ecole Nationale Supérieure de Chimie de Mulhouse-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Matériaux à Porosité Contrôlée (LMPC) |
| Jazyk: | angličtina |
| Rok vydání: | 1999 |
| Předmět: |
Stereochemistry
Nucleation chemistry.chemical_element 02 engineering and technology Crystal structure 010402 general chemistry Molecular sieve 01 natural sciences law.invention law [CHIM]Chemical Sciences General Materials Science Crystallization Zeolite Inductive effect ComputingMilieux_MISCELLANEOUS Plane (geometry) General Chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 0104 chemical sciences Crystallography chemistry Mechanics of Materials 0210 nano-technology Cobalt |
| Zdroj: | Microporous and Mesoporous Materials Microporous and Mesoporous Materials, Elsevier, 1999, 33 (1-3), pp.143-148. ⟨10.1016/S1387-1811(99)00132-8⟩ |
| ISSN: | 1387-1811 |
| DOI: | 10.1016/S1387-1811(99)00132-8⟩ |
| Popis: | The addition of as-synthesized UTD-1 seeds to an SSZ-24 synthesis mixture accelerates the zeolite nucleation and leads to the formation of pure and well-crystallized SSZ-24. Computer modeling showed that the (001) cleavage plane in the UTD-1 framework fits perfectly to the (110) in the SSZ-24 structure. Subunits extracted from the (001) plane and stabilized by the bis-(pentamethylcyclopentadienyl) cobalt(III) complex may be viable precursors for zeolite SSZ-24. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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