Synthesis of End-Group Functionalized P3HT: General Protocol for P3HT/Nanoparticle Hybrids

Autor:	Alfons Smeets, Pascal Gerbaux, Frederic Monnaie, Julien De Winter, Guy Koeckelberghs, Thierry Verbiest, Ward Brullot
Rok vydání:	2013
Předmět:	chemistry.chemical_classification Polymers and Plastics Organic Chemistry Nanoparticle Inorganic Chemistry chemistry.chemical_compound End-group Polymerization chemistry Pyridine Polymer chemistry Materials Chemistry Thiol Surface modification Phenol Hybrid material
Zdroj:	Macromolecules. 46:8500-8508
ISSN:	1520-5835 0024-9297 8500-8508
DOI:	10.1021/ma401809e
Popis:	Poly(3-hexylthiophene)s were synthesized with phosphonic ester, pyridine, thiol, and phenol end-groups using functionalized air-stable Ni initiators. The protected thiol- and phenol-functionalized P3HTs were converted into thiol and phenol P3HTs by quantitative postpolymerization reactions. 1H NMR and MALDI-ToF analysis showed very high degrees of functionalization and strong control over the polymerization except for the pyridine functionalized P3HT. These functional end-groups were used to prepare hybrid materials from a broad variety of nanoparticles, including metal oxides, quantum dots, and noble metals. © 2013 American Chemical Society. ispartof: Macromolecules vol:46 issue:21 pages:8500-8508 status: published
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e1ec37b7caa1274d6b0cfb14fb8c33d4 https://doi.org/10.1021/ma401809e Zobrazit plný text záznamu