Supramolecular control of reverse spin transitions in cobalt( ii ) terpyridine complexes with diblock copolypeptide amphiphiles
| Autor: | Tsubasa Arie, Shinichi Sakurai, Keita Kuroiwa, Shinya Hayami, Timothy J. Deming |
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| Rok vydání: | 2015 |
| Předmět: |
Materials science
Spin transition Supramolecular chemistry chemistry.chemical_element General Chemistry Materials Engineering Macromolecular and Materials Chemistry chemistry.chemical_compound chemistry Amphiphile Polymer chemistry Materials Chemistry Terpyridine Spin (physics) Cobalt Physical Chemistry (incl. Structural) |
| Zdroj: | Journal of Materials Chemistry C, vol 3, iss 30 Kuroiwa, K; Arie, T; Sakurai, S; Hayami, S; & Deming, TJ. (2015). Supramolecular control of reverse spin transitions in cobalt(II) terpyridine complexes with diblock copolypeptide amphiphiles. Journal of Materials Chemistry C, 3(30), 7779-7783. doi: 10.1039/c5tc00677e. UCLA: Retrieved from: http://www.escholarship.org/uc/item/6s51g31f |
| DOI: | 10.1039/c5tc00677e. |
| Popis: | © The Royal Society of Chemistry 2015. Three composites composed of the cobalt terpyridine complex [CoII(MeO-terpy)2] and the diblock copolypeptide amphiphiles 1 and 2 or the polypeptide 3 (including glutamic acid and leucine) were prepared. Supramolecular structures such as rectangular morphologies were obtained from composites of 1 and 2. A perfectly reversible reverse spin transition was successfully generated in the case of composites made with 1. |
| Databáze: | OpenAIRE |
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