Crystal structure of 2,2′-bipyridine-1,1′-diium tetrachloridozincate
| Autor: | Krishnamoorthy Anbalagan, Subramani Thirumurugan, Jeyaraman Govindaraj, A. SubbiahPandi, Antoni Samy Clara |
|---|---|
| Rok vydání: | 2015 |
| Předmět: |
chemistry.chemical_classification
crystal structure tetrachloridozincate Hydrogen bond Salt (chemistry) Nanotechnology General Chemistry Crystal structure Dihedral angle hydrogen bonding Condensed Matter Physics Data Reports 2 2′-bipyridine-1 1′-diium Dication lcsh:Chemistry Crystal chemistry.chemical_compound Crystallography lcsh:QD1-999 chemistry Pyridine 2 2′-bipyridine-1 1′-diium General Materials Science tetrachloridozincate Zincate |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 3, Pp m67-m68 (2015) |
| ISSN: | 2056-9890 |
| DOI: | 10.1107/s2056989015003175 |
| Popis: | In the crystal structure of the title salt, (C10H10N2)[ZnCl4], the bipyridinediium dication is not planar, with a dihedral angle of 37.21 (9)° between the planes of the two pyridine rings. In the crystal, the slightly distorted [ZnCl4]2−anions are packed into rods parallel to [001], with the organic cations arranged in corrugated layers parallel to (100). Cations and anions are linked through N—H...Cl hydrogen bonds, forming chains parallel to [20-1]. Additional C—H...Cl interactions consolidate the crystal packing. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|