Incorporating BODIPY Fluorophores into Tetrakis(arylethynyl)benzenes

Autor:	Brian S. Young, Daniel T. Chase, Michael M. Haley
Rok vydání:	2011
Předmět:	chemistry.chemical_classification Organic Chemistry Electron donor Electron acceptor Chromophore Photochemistry Medicinal chemistry Acceptor Dibutylamine chemistry.chemical_compound chemistry Structural isomer Molecule BODIPY
Zdroj:	The Journal of Organic Chemistry. 76:4043-4051
ISSN:	1520-6904 0022-3263
Popis:	Six structural isomers of a tetrakis(arylethynyl)benzene (TAEB) chromophore functionalized with dibutylamine and BODIPY moieties as the corresponding donor and acceptor units were prepared. To evaluate the effectiveness of the donor group, two TAEB molecules and three structurally related bis(arylethynyl)benzene (BAEB) isomers containing only acceptors were also synthesized. The electronic absorption and emission spectra of each series were examined. Additionally, computational studies were employed to corroborate the relative energy levels and gaps present in each series.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e128c3fa50e708567e3304c726c92201 https://doi.org/10.1021/jo200491m Zobrazit plný text záznamu